Third-order relativistic many-body calculations of energies and lifetimes of levels along the silver isoelectronic sequence

Energies of 5l_j (l= s, p, d, f, g) and 4f_j states in neutral Ag and Ag-like ions with nuclear charges Z = 48 - 100 are calculated using relativistic many-body perturbation theory. Reduced matrix elements, oscillator strengths, transition rates and lifetimes are calculated for the 17 possible 5l_j-5l'_{j'} and 4f_j-5l_{j'} electric-dipole transitions. Third-order corrections to energies and dipole matrix elements are included for neutral Ag and for ions with Z60. Comparisons are made with available experimental data for transition energies and lifetimes. Correlation energies and transition rates are shown graphically as functions of nuclear charge Z for selected cases. These calculations provide a theoretical benchmark for comparison with experiment and theory.Comment: 8 page

Relativistic many-body calculations of energies of n=3 states in aluminumlike ions

Energies of 3l3l′3l″ states of aluminumlike ions with Z=14?100 are evaluated to second order in relativistic many-body perturbation theory starting from a 1s22s22p6 Dirac-Fock potential. Intrinsic three-particle contributions to the energy are included in the present calculation and found to contribute about 10?20 % of the total second-order energy. Corrections for the frequency-dependent Breit interaction and the Lamb shift are included in lowest order. A detailed discussion of contributions to the energy levels is given for aluminumlike germanium (Z=32). Comparisons are made with available experimental data. We obtain excellent agreement for term splitting, even for low-Z ions. These calculations are presented as a theoretical benchmark for comparison with experiment and theory

Electric-dipole, electric-quadrupole, magnetic-dipole, and magnetic-quadrupole transitions in the neon isoelectronic sequence

Excitation energies for 2l-3l′ hole-particle states of Ne-like ions are determined to second order in relativistic many-body perturbation theory (MBPT). Reduced matrix elements, line strengths, and transition rates are calculated for electric-dipole (E1), magnetic-quadrupole (E2), magnetic-dipole (M1), and magnetic-quadrupole (M2) transitions in Ne-like ions with nuclear charges ranging from Z=11 to 100. The calculations start from a 1s22s22p6 closed-shell Dirac-Fock potential and include second-order Coulomb and Breit-Coulomb interactions. First-order many-body perturbation theory (MBPT) is used to obtain intermediate-coupling coefficients, and second-order MBPT is used to determine the matrix elements. Contributions from negative-energy states are included in the second-order E1, M1, E2, and M2 matrix elements. The resulting transition energies are compared with experimental values and with results from other recent calculations. Trends of E1, E2, M1, and M2 transition rates as functions of nuclear charge Z are shown graphically for all transitions to the ground state

Multipole (E1, M1, E2, M2, E3, M3) transition wavelengths and rates between 3l5l' excited and ground states in nickel-like ions

A relativistic many-body method is developed to calculate energy and transition rates for multipole transitions in many-electron ions. This method is based on relativistic many-body perturbation theory (RMBPT), agrees with MCDF calculations in lowest-order, includes all second-order correlation corrections and includes corrections from negative energy states. Reduced matrix elements, oscillator strengths, and transition rates are calculated for electric-multipole (dipole (E1), quadrupole (E2), and octupole (E3)) and magnetic-multipole (dipole (M1), quadrupole (M2), and octupole (M3)) transitions between 3l5l' excited and ground states in Ni-like ions with nuclear charges ranging from Z = 30 to 100. The calculations start from a 1s22s22p63s23p63d10} Dirac-Fock potential. First-order perturbation theory is used to obtain intermediate-coupling coefficients, and second-order RMBPT is used to determine the matrix elements. A detailed discussion of the various contributions to the dipole matrix elements and energy levels is given for nickellike tungsten (Z = 74). The contributions from negative-energy states are included in the second-order E1, M1, E2 M2, E3, and M3 matrix elements. The resulting transition energies and transition rates are compared with experimental values and with results from other recent calculations. These atomic data are important in modeling of M-shell radiation spectra of heavy ions generated in electron beam ion trap experiments and in M-shell diagnostics of plasmas.Comment: 21 pages, 8 figures, 11 table